Physical Chemistry book , 3rd edition by Robert G. Mortimer
preface of This book
The book is divided into four parts.
The first part focuses on the macroscopic properties of physical systems. It
begins with the descriptive study of gases and liquids, and proceeds to the study
of thermodynamics, which is a comprehensive macroscopic theory of the behavior
of material systems. The second part focuses on dynamics, including gas kinetic
theory, transport processes, and chemical reaction kinetics. The third part
presents quantum mechanics and spectroscopy. The fourth part presents the relationship
between molecular and macroscopic properties of systems through the study of
statistical mechanics. This theory is applied to the structure of condensed phases.
The book is designed so that the first three parts can be studied in any order,
while the fourth part is designed to be a capstone in which the other parts are
integrated into a cohesive whole.
Answers to all of the numerical exercises and
to the odd-numbered numerical problems are placed in Appendix K. A solutions
manual, with complete solutions to all exercises and all odd numbered problems,
is available from the publisher. An instructor’s manual with solutions to the
even-numbered problems is available on-line to instructors. The instructor can
choose whether to allow students to have access to the solutions manual, but
can assign even-numbered problems when he or she wants the students to work
problems without access to solutions.
In addition to the standard tables of integrals and numerical values of
various properties, the book contains several appendices that expand on
discussions in the body of the text, such as more detailed discussions of
perturbation theory, group theory, and several mathematical topics. Each
chapter begins with a statement of the principal facts and ideas that are
presented in the chapter. There is a summary at the end of each chapter to
assist in synthesizing the material of each chapter into a coherent whole.
There are also marginal notes throughout the chapters that present biographical
information and some comments. Each chapter contains examples that illustrate
various kinds of calculations, as well as exercises placed within the chapter.
Both these exercises and the problems at the end of each section are designed
to provide practice in applying techniques and insights obtained through study
of the chapter.
Description of the book
Book name:
Physical Chemistry, 3rd edition by Robert G. Mortimer .
Author:
Robert G. Mortimer
Professor Emeritus
Rhodes College
Memphis, Tennessee
Edition: 3rd edition
Year: 2008
No of Chapters: 28
No of Pages: 1405
File format: pdf
File size: 10.5 MB
Contents
PART (I): Thermodynamics and the Macroscopic Description of
Physical Systems
Chapter 1: The
Behavior of Gases and Liquids
Chapter 2: Work, Heat, and Energy: The First Law of Thermodynamics
Chapter 3: The
Second and Third Laws of Thermodynamics: Entropy
Chapter 4: The
Thermodynamics of Real Systems
Chapter 5: Phase
Equilibrium
Chapter 6: The
Thermodynamics of Solutions
Chapter 7: Chemical Equilibrium
Chapter 8: The
Thermodynamics of Electrochemical Systems
PART (II): Dynamics
Chapter 9: Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium
Chapter 10: Transport
Processes
Chapter 11: The
Rates of Chemical Reactions
Chapter 12: Chemical Reaction Mechanisms I: Rate Laws and Mechanisms
Chapter 13: Chemical Reaction Mechanisms II: Catalysis and
Miscellaneous Topics
PART (III): The Molecular Nature of Matter
Chapter 14: Classical Mechanics and the Old Quantum Theory
Chapter 15: The Principles of Quantum Mechanics. I. De
BroglieWaves and the Schrodinger Equation
Chapter 16: The Principles of Quantum Mechanics. II.
The Postulates of Quantum Mechanics
Chapter 17: The
Electronic States of Atoms. I. The Hydrogen Atom
Chapter 18: The Electronic States ofAtoms. II.The
Zero-OrderApproximation for Multielectron Atoms
Chapter 19: The Electronic States of Atoms. III.
Higher-Order Approximations
Chapter 20: The
Electronic States of Diatomic Molecules
Chapter 21: The
Electronic Structure of Polyatomic Molecules
Chapter 22: Translational, Rotational, and Vibrational
States of Atoms and Molecules
Chapter 23: Optical
Spectroscopy and Photochemistry
Chapter 24: Magnetic
Resonance Spectroscopy
PART (IV): The Reconciliation of the Macroscopic and Molecular Theories of Matter
Chapter 25: Equilibrium
Statistical Mechanics I. The Probability Distribution for Molecular States
Chapter 26: Equilibrium Statistical Mechanics. II.
Statistical Thermodynamics
Chapter 27: Equilibrium
Statistical Mechanics. III. Ensembles
Chapter 28: The
Structure of Solids, Liquids, and Polymers
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